13058-45-2

Usage

Uses

Used in Industrial Applications:
Ethanone, 1-(3-hexyloxiranyl)is utilized as an intermediate in the synthesis of various industrial products. The hexyloxiranyl group contributes to the compound's reactivity and versatility, allowing it to be incorporated into a wide range of materials.
Used in Pharmaceutical Applications:
In the pharmaceutical industry, Ethanone, 1-(3-hexyloxiranyl)serves as a key component in the development of new drugs. Its unique structure allows it to interact with biological targets, making it a promising candidate for the treatment of various diseases.
Used in Chemical Synthesis:
Ethanone, 1-(3-hexyloxiranyl)is employed as a building block in the synthesis of complex organic molecules. Its reactivity and the presence of the hexyloxiranyl group make it a valuable tool for chemists in creating novel compounds with specific properties.
Used in Surface Coating Applications:
Ethanone, 1-(3-hexyloxiranyl)is also used in the formulation of surface coatings, where its unique properties can enhance the performance of the coatings. The hexyloxiranyl group can improve adhesion, durability, and other characteristics of the coatings, making them suitable for various applications.

Upstream product

• 360573-52-0 C₆H₁₀O₂ 
• 18402-84-1 (3E)-dec-3-en-2-one 

Downstream Products

• 38836-24-7 4-hydroxy-decan-2-one 
• 24892-56-6 Decane-2,4-diol 
• 3848-26-8 decane-2,3-dione 

Relevant academic research and scientific papers

The cinchona primary amine-catalyzed asymmetric epoxidation and hydroperoxidation of α,β-unsaturated carbonyl compounds with hydrogen peroxide

Using cinchona alkaloid-derived primary amines as catalysts and aqueous hydrogen peroxide as the oxidant, we have developed highly enantioselective Weitz-Scheffer-type epoxidation and hydroperoxidation reactions of α,β-unsaturated carbonyl compounds (up to 99.5:0.5 er). In this article, we present our full studies on this family of reactions, employing acyclic enones, 5-15-membered cyclic enones, and α-branched enals as substrates. In addition to an expanded scope, synthetic applications of the products are presented. We also report detailed mechanistic investigations of the catalytic intermediates, structure-activity relationships of the cinchona amine catalyst, and rationalization of the absolute stereoselectivity by NMR spectroscopic studies and DFT calculations.

A Halide-Free Method for Olefin Epoxidation with 30% Hydrogen Peroxide

A catalytic system consisting of sodium tungstate dihydrate, (aminomethyl) phosphonic acid, and methyltrioctylammonium Hydrogensulfate, effects the epoxidation of olefins using 30% hydrogen peroxide with a substrate-to-catalyst molar ratio of 50 - 500. The reaction proceeds in high yield without solvents, or, alternatively, with added toluene under entirely halide-free conditions. Lipophilic ammonium hydrogensulfate, which replaces the conventional chloride, and an (α-aminoalkyl)phosphonic acid are crucial for the high reactivity. This method is operationally simple, environmentally benign, and much more economical than the oxidation with m-chloroperbenzoic acid, allowing for a large-scale preparation of epoxides. Various substrates including terminal olefins, 1,1- and 1,2-disubstituted olefins, cyclic olefins, and tri- and tetrasubstituted olefins as well as allylic alcohols, esters, α,β-unsaturated ketones, and ethers can be epoxidized in high yield. The scope and limitations of this new reaction system are discussed.