24892-56-6Relevant academic research and scientific papers
Autoxidation of Nonane and Decane: A Product Study
Goosen, Andre,Morgan, David H.
, p. 557 - 562 (2007/10/02)
The autoxidation of nonane and decane has been shown to occur in three stages.The initial stage leads to alkyl hydroperoxide formation and in the second stage the hydroperoxide decomposes to produce alcohols and ketones as major products.These studies sup
Electroreductive Ring-Opening of α,β-Epoxy Carbonyl Compounds and Their Homologues through Recyclable Use of Diphenyl Diselenide or Diphenyl Ditelluride as a Mediator
Inokuchi, Tsutomu,Kusumoto, Masahiko,Torii, Sigeru
, p. 1548 - 1553 (2007/10/02)
A novel access to β-hydroxy carbonyl compounds from the corresponding α,β-epoxy compounds has been attained through the recyclable use of diphenyl diselenide or diphenyl ditelluride as an electroreduction mediator in a MeOH-NaClO4-(Pt) system. α,β-Epoxy ketones are converted to the corresponding aldols in the presence of malonic esters.Similarly, α,β-epoxy esters and nitriles can be reduced to the corresponding β-hydroxy compounds in the presence of acetic acid.
