130612-85-0Relevant academic research and scientific papers
KI-catalyzed C-S bond formation: Via an oxidation relay strategy: Efficient access to various α-thio-β-dicarbonyl compounds
Jiang, Yi,Zou, Jiao-Xia,Huang, Long-Tao,Peng, Xue,Deng, Jie-Dan,Zhu, Long-Qing,Yang, Yu-Hang,Feng, Yi-Yue,Zhang, Xiao-Yun,Wang, Zhen
, p. 1641 - 1645 (2018/03/21)
An efficient and practical methodology to obtain α-thio-β-dicarbonyl compounds was presented under alkaline conditions via potassium iodide (KI) catalysis; various symmetrical/unsymmetrical 1,3-dicarbonyl compounds were obtained under an aerobic atmospher
Sulfur Assisted Tandem Electrophilic Fluorinative Deacylation: Synthesis of α-Fluoro β-Ketosulfides
Varun, Begur Vasanthkumar,Prabhu, Kandikere Ramaiah
, p. 9525 - 9536 (2017/09/23)
A successful synthesis of α-fluoro-β-ketosulfides using an electrophilic fluorination method has been reported for the first time. The reaction proceeds via an electrophilic fluorination of α-sulfenyl-β-diketones followed by an unexpected tandem deacylation. The resulting products, α-fluoro-β-ketosulfides, are easily oxidized to the corresponding α-fluoro-β-ketosulfones, which can be used for further useful olefination reactions.
Highly selective electrochemical fluorination of dithioacetal derivatives bearing electron-withdrawing substituents at the position α to the sulfur atom using poly(HF) salts
Yin, Bin,Inagi, Shinsuke,Fuchigami, Toshio
supporting information, p. 85 - 91 (2015/02/05)
Anodic fluorination of dithioacetals bearing electron-withdrawing ester, acetyl, amide, and nitrile groups at their α-positions was comparatively studied using various supporting poly(HF) salts like Et3N·nHF (n = 3-5) and Et4NF·nHF (
Electrolytic Partial Fluorination of Organic Compounds. 17. Regiospecific Anodic Fluorination of Sulfides Bearing Electron-Withdrawing Substituents at the Position α to the Sulfur Atom
Fuchigami, Toshio,Shimojo, Moriyasu,Konno, Akinori
, p. 3459 - 3464 (2007/10/02)
Regiospecific monofluorination of various sulfides bearing electron-withdrawing substituents, cyano, ester, acyl, amino, and phosphonate groups, at their α-positions was successfully carried out by the anodic oxidation of the sulfides in Et3N*3HF/MeCN usi
Electrolytic Partial Fluorination of Organic Compounds. Regioselective Anodic Monofluorination of Organosulfur Compounds
Fuchigami, Toshio,Shimojo, Moriyasu,Konno, Akinori,Nakagawa, Kiyono
, p. 6074 - 6075 (2007/10/02)
Regioselective anodic monofluorination of aryl 2,2,2-trifluoroethyl sulfides gave, exclusively, aryl 1,2,2,2-tetrafluoroethyl sulfides, the products of fluorination at the position α to the trifluoromethyl group.The α-monofluorination of sulfides bearing
