130633-33-9

Upstream product

• 3260-88-6 1-chloro-3-methoxy-2-methylbenzene 
• 109838-85-9 (2R)-2,5-dihydro-2-isopropyl-3,6-dimethoxypyrazine 
• 130633-31-7 (R)-N-tert-butoxycarbonyl-3-hydroxyphenylglycine methyl ester 
• 25698-27-5 (R)-3-hydroxyphenylglycine 
• 130697-96-0 3-hydroxyphenylglycine methyl ester 
• 87-60-5 3-chloro-2-methylbenzenamine 

Downstream Products

• 130633-35-1 (S)-Amino-{3-[3-((R)-amino-methoxycarbonyl-methyl)-phenoxy]-5-methoxy-4-methyl-phenyl}-acetic acid methyl ester 
• 130633-34-0 (S)-Amino-{3-[3-((R)-tert-butoxycarbonylamino-methoxycarbonyl-methyl)-phenoxy]-5-methoxy-4-methyl-phenyl}-acetic acid methyl ester 

Relevant academic research and scientific papers

Synthesis of a Deoxyristomycinic Acid Derivative using Organomanganese Chemistry

Coupling of (3-chloro-2-methylanisole)tricarbonylmanganese tetrafluoroborate with the phenoxide derived from methyl N-Boc-3-hydroxyphenylglycinate gave the diaryl ether manganese complex (6).This complex underwent regiospecific, stereoselective reaction with Schollkopf's chiral glycine enolate equivalent to give a mixture of dienyl-Mn(CO)3 complexes that were converted in a two-step sequence into the protected deoxyristomycinic acid derivative (12).