130633-31-7

Basic information

• Product Name: (R)-N-tert-butoxycarbonyl-3-hydroxyphenylglycine methyl ester
• Synonyms: (R)-N-tert-butoxycarbonyl-3-hydroxyphenylglycine methyl ester
• CAS NO: 130633-31-7
• Molecular Weight: 281.309
• Mol File: 130633-31-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (R)-N-tert-butoxycarbonyl-3-hydroxyphenylglycine methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-N-tert-butoxycarbonyl-3-hydroxyphenylglycine methyl ester(130633-31-7)
• EPA Substance Registry System: (R)-N-tert-butoxycarbonyl-3-hydroxyphenylglycine methyl ester(130633-31-7)

Safety Data

• Hazardous Substances Data: 130633-31-7(Hazardous Substances Data)

Upstream product

• 34619-03-9 tert-butyldicarbonate 
• 130697-96-0 3-hydroxyphenylglycine methyl ester 
• 25698-27-5 (R)-3-hydroxyphenylglycine 
• 24424-99-5 di-tert-butyl dicarbonate 
• 136057-18-6 (R)-3-hydroxyphenylglycine methyl ester hydrochloride 

Downstream Products

• 130633-34-0 (S)-Amino-{3-[3-((R)-tert-butoxycarbonylamino-methoxycarbonyl-methyl)-phenoxy]-5-methoxy-4-methyl-phenyl}-acetic acid methyl ester 
• 130633-35-1 (S)-Amino-{3-[3-((R)-amino-methoxycarbonyl-methyl)-phenoxy]-5-methoxy-4-methyl-phenyl}-acetic acid methyl ester 
• 136057-28-8 (R)-4-{3-[4-((R)-2-[(R)-2-Benzyloxycarbonylamino-2-(4-hydroxy-phenyl)-acetylamino]-2-{[(S)-tert-butoxycarbonyl-(4-tert-butoxy-phenyl)-methyl]-carbamoyl}-ethyl)-phenoxy]-phenyl}-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester 
• 136057-27-7 (R)-4-{3-[4-((R)-2-Azido-2-{[(S)-tert-butoxycarbonyl-(4-tert-butoxy-phenyl)-methyl]-carbamoyl}-ethyl)-phenoxy]-phenyl}-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester 
• 136057-23-3 (R)-4-(3-{4-[3-((R)-4-Benzyl-2-oxo-oxazolidin-3-yl)-3-oxo-propyl]-phenoxy}-phenyl)-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester 
• 136057-31-3 (3-{4-[3-((R)-1-Amino-2-hydroxy-ethyl)-phenoxy]-phenyl}-propionylamino)-acetic acid; hydrochloride 
• 136057-30-2 (R)-4-(3-{4-[2-(tert-Butoxycarbonylmethyl-carbamoyl)-ethyl]-phenoxy}-phenyl)-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester 
• 136057-21-1 (R)-4-{3-[4-(2-Methoxycarbonyl-ethyl)-phenoxy]-phenyl}-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester 
• 136057-20-0 (R)-4-{3-[4-((E)-2-Methoxycarbonyl-vinyl)-phenoxy]-phenyl}-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester 
• 136057-22-2 (R)-4-{3-[4-(2-Carboxy-ethyl)-phenoxy]-phenyl}-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester 
• 136057-19-7 N-tert-butoxycarbonyl-2,2'-dimethyl-4-(3-hydroxyphenyl)-1,3-oxazolidine 
• 136083-50-6 N-tert-butoxycarbonyl-2-hydroxy-1-(3-hydroxyphenyl)-ethylamine 
• 130633-32-8 methyl phenylglycinate 
• 130633-33-9 (R)-tert-Butoxycarbonylamino-{3-[5-((2S,5R)-5-isopropyl-3,6-dimethoxy-2,5-dihydro-pyrazin-2-yl)-3-methoxy-2-methyl-phenoxy]-phenyl}-acetic acid methyl ester 

Relevant articles and documents

Silicon-Directed Diene Synthesis

A synthesis of 2-substituted-1,3-dienes is reported which uses silicon as a control element: eight aldehydes were converted into α-silyl ketones by treatment with trimethylsilylmethylmagnesium chloride and rapid Collins oxidation.Addition of vinylmagnesiu

Synthesis of a Deoxyristomycinic Acid Derivative using Organomanganese Chemistry

Coupling of (3-chloro-2-methylanisole)tricarbonylmanganese tetrafluoroborate with the phenoxide derived from methyl N-Boc-3-hydroxyphenylglycinate gave the diaryl ether manganese complex (6).This complex underwent regiospecific, stereoselective reaction with Schollkopf's chiral glycine enolate equivalent to give a mixture of dienyl-Mn(CO)3 complexes that were converted in a two-step sequence into the protected deoxyristomycinic acid derivative (12).