130659-33-5Relevant academic research and scientific papers
Highly regioselective hydrosilylation of unsymmetric alkynes using a phenylthio directing group
Huang, Kuan-Hsun,Isobe, Minoru
, p. 4733 - 4740 (2014/08/05)
Cobalt-assisted hydrosilylation of acetylenes is particularly interesting in organic synthesis since alkynyl group functionalization can give way to more useful substructures. This study aims to answer the general question of how to control hydrosilylatio
Nickel-palladium-catalyzed hydroamination/cyclization of sulfur-substituted 1,6-diynes with secondary amines
Nagata, Hayami,Sugimoto, Yuko,Ito, Yukiteru,Tanaka, Miki,Yoshimatsu, Mitsuhiro
, p. 1306 - 1316 (2014/02/14)
Hydroamination/cyclizations of sulfur-substituted 1,6-diynes catalyzed by nickel or nickel-palladium in DMSO were examined. Pyrroles 2a-l and furans 5a-i bearing various secondary amines were obtained in high yields. The organosulfanylmethyl group on pyrr
Short and efficient preparation of alkynyl selenides, sulfides and tellurides from terminal alkynes
Bieber, Lothar W.,Da Silva, Margarete F.,Menezes, Paulo H.
, p. 2735 - 2737 (2007/10/03)
Diphenyl diselenide reacts with terminal alkynes at room temperature in DMSO in the presence of catalytic amounts of copper iodide to give good to excellent yields of alkynyl phenyl selenides. The reaction occurs under neutral conditions and the solvent a
An efficient and general synthesis of alkynyl sulfoxides
Kabanyane, Sidima T.,MaGee, David I.
, p. 2758 - 2763 (2007/10/02)
A convenient one-step method for the preparation of alkynyl phenyl sulfides using diphenyl disulfide has been developed.The oxidation of the corresponding sulfides to the sulfoxides, and not sulfones, was achieved by using trans-(phenylsulfonyl)-3-phenyloxaziridine.A variety of other oxidizing reagents was also investigated.
Stereoselective construction and synthetic applications of phenylthio substituted iodoolefins
Magriotis,Doyle,Kim
, p. 2541 - 2544 (2007/10/02)
(E)- and (Z)-Phenylthio substituted iodoolefins 1 and 2 have been synthesized stereoselectively via lower order stannylcuprate addition to and hydroalumination of appropriate alkyne precursors. Their utility in model studies on the synthesis of calichemic
