130712-09-3Relevant academic research and scientific papers
Palladium-catalyzed carboxylative coupling of benzyl chlorides with allyltributylstannane: Remarkable effect of palladium nanoparticles
Feng, Xiujuan,Sun, Anle,Zhang, Sheng,Yu, Xiaoqiang,Bao, Ming
supporting information, p. 108 - 111 (2013/04/10)
Palladium-catalyzed carboxylative coupling of benzyl chlorides with allyltributylstannane was successfully conducted to produce benzyl but-3-enoates in satisfactory to good yields. The carboxylative coupling reaction occurred smoothly under mild conditions in the presence of palladium nanoparticles in tetrahydrofuran.
Kinetics of Reaction of p-Nitrobenzyl Bromide with Some α,β-Unsaturated Carboxylate Ions
Chandrasekharan, J.
, p. 327 - 328 (2007/10/02)
The second-order rate constants for the reaction of p-nitrobenzyl bromide with the mono- and dianions of maleic and fumaric acids, and with cinnamate, crotonate and acetate ions have been determined in 60percent acetone-water (v/v) at 30 deg C, 35 deg C and 40 deg C.The reactivity decreases in the order: maleate dianion > cinnamate > fumarate dianion > crotonate > acetate > fumarate monoanion > maleate monoanion.
