130716-13-1

Basic information

• Product Name: (3,3,3-trifluoroprop-1-en-1-ylidene)cyclohexane
• Synonyms: (3,3,3-trifluoroprop-1-en-1-ylidene)cyclohexane
• CAS NO: 130716-13-1
• Molecular Weight: 176.182
• Mol File: 130716-13-1.mol

Chemical Properties

• CAS DataBase Reference: (3,3,3-trifluoroprop-1-en-1-ylidene)cyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: (3,3,3-trifluoroprop-1-en-1-ylidene)cyclohexane(130716-13-1)
• EPA Substance Registry System: (3,3,3-trifluoroprop-1-en-1-ylidene)cyclohexane(130716-13-1)

Safety Data

• Hazardous Substances Data: 130716-13-1(Hazardous Substances Data)

Upstream product

• 6209-75-2 1-ethynyl-1-chlorocyclohexane 
• 77152-08-0 trifluoromethylcopper(I) 
• 325810-07-9 tris(triphenylphosphane)(trifluoromethyl)copper(I) 

Relevant articles and documents

Trifluoromethylation of propargylic halides and trifluoroacetates using (Ph3P)3Cu(CF3) reagent

A copper-mediated trifluoromethylation of propargylic halides and trifluoroacetates was performed with high allenyl or propargyl selectivity. The reaction proceeds smoothly with aliphatic and aromatic substituents bearing either electron-withdrawing or -s

A facile, general route to perfluoroalkyl allenes

Perfluoroalkyl copper reagents react with propargyl halides or tosylates in DMF or DMSO at 0°C-RT to afford perfluoroalkyl allenes regiospecifically in good yield.