130719-83-4Relevant articles and documents
Formation and reactivvity of 1-pyrrolyl-2,2,2-trifluoroethyl cations
Allen, Annette D.,Kwong-Chip, Jean-Marc,Lin, Wing Cheung,Nguyen, Paul,Tidwell, Thomas T.
, p. 1709 - 1713 (2007/10/02)
1-(1-Methyl-2-pyrrolyl)-2,2,2-trifluoroethyl p-nitrobenzoate (3) reacts by carbocation formation with an m value for the dependence of rate on the solvent polarity parameter YOTs of 0.56, and a rate 41 times slower than (1-methyl-2-pyrrolyl) me