130735-35-2

Upstream product

• 130735-31-8 (1R*,2R*)-2-hydroxymethyl-1,2-dimethylcyclopentaneethanol 
• 125318-22-1 (1R*,6R*)-1,6-dimethyl-3-oxabicyclo<4.3.0>nonan-4-one 
• 130735-32-9 (1R*,2R*)-1,2-dimethyl-2-(2-triphenylmethoxyethyl)cyclopentanemethanol 

Downstream Products

• 110351-79-6 (1'R,2'R)-bifurcarenone 
• 130852-52-7 (1R,2R)-1,2-dimethyl-2-(2-triphenylmethoxyethyl)cyclopentanemethanol 
• 125318-34-5 (1'R,2'R,4E)-2-(2'-t-butyldimethylsiloxymethyl-1',2'-dimethylcyclopentylmethyl)-2-ethoxyethoxy-6-<2,5-bis(methoxymethoxy)-3-methylphenyl>-4-methyl-4-hexenenitrile 
• 125318-44-7 (1'R,2'R,4E)-6-(5-t-butyldimethylsiloxy-2-hydroxy-3-methylphenyl)-1-<2'-(1,4-dihydroxy-4-methyl-2-pentynyl)-1',2'-dimethylcyclopentyl>-4-methyl-4-hexen-2-yl pivalate 
• 125318-40-3 (1'R,2'R,4E)-1-<2'-(1,4-dihydroxy-4-methyl-2-pentynyl)-1',2'-dimethylcyclopentyl>-6-<2,5-bis(methoxymethoxy)-3-methylphenyl>-4-methyl-4-hexen-2-yl pivalate 
• 125318-37-8 (1'R,2'R,4E)-1-(2'-t-butyldimethylsiloxymethyl-1',2'-dimethylcyclopentyl)-6-<2,5-bis(methoxymethoxy)-3-methylphenyl>-4-methyl-4-hexen-2-yl pivalate 
• 130852-46-9 (1'R,2'R,2''E,4E)-6-(5-t-butyldimethylsiloxy-2-hydroxy-3-methylphenyl)-1-<1',2'-dimethyl-2'-(4''-hydroxy-4''-methyl-2''-pentenoyl)cyclopentyl>-4-methyl-4-hexen-2-one 
• 130852-41-4 (1'R,2'R,4E)-1-(2'-t-butyldimethylsiloxymethyl-1',2'-dimethylcyclopentyl)-6-<2,5-bis(methoxymethoxy)-3-methylphenyl>-4-methyl-4-hexen-2-one 
• 125318-39-0 (1'R,2'R,4E)-1-(2'-formyl-1',2'-dimethyl-2'-hydroxymethylcyclopentyl)-6-<2,5-bis(methoxymethoxy)-3-methylpehnyl>-4-methyl-4-hexen-2-yl pivalate 
• 125318-45-8 (1'R,2'R,2''E,4E)-6-(5-t-butyldimethylsiloxy-2-hydroxy-3-methylphenyl)-1-<2'-(1'',4''-dihydroxy-4''-methyl-2''-pentynyl)-1',2'-dimethylcyclopentyl>-4-methyl-4-hexen-2-ol 
• 125318-36-7 (1'R,2'R,4E)-1-(2'-t-butyldimethylsiloxymethyl-1',2'-dimethylcyclopentyl)-6-<2,5-bis(methoxymethoxy)-3-methylphenyl>-4-methyl-4-hexen-2-ol 
• 125318-38-9 (1'R,2'R,4E)-1-(1',2'-dimethyl-2'-hydroxymethylcyclopentyl)-6-<2,5-bis(methoxymethoxy)-3-methylpehnyl>-4-methyl-4-hexen-2-yl pivalate 
• 130735-37-4 (1R,2R)-1-t-butyldimethylsiloxymethyl-1,2-dimethyl-2-(2-triphenylmethoxyethyl)cyclopentane 
• 130735-30-7 (1R,4aS,7aS)-1-((1S,2R,5S)-2-Isopropyl-5-methyl-cyclohexyloxy)-4a,7a-dimethyl-octahydro-cyclopenta[c]pyran 

Relevant academic research and scientific papers

DETERMINATION OF THE ABSOLUTE CONFIGURATION OF BIFURCARENONE BY THE SYNTHESIS OF ITS (1'R,2'R)-ISOMER

(1'R,2'R)-Isomer of bifurcarenone (1) was synthesized.By comparing its ORD spectrum with that of the natural product, the marine C27 hydroquinone isolated as an inhibitor of mitoic cell division was shown to be (1'S,2'S)-1.