1307474-73-2Relevant academic research and scientific papers
Synthesis and application of palladium precatalysts that accommodate extremely bulky Di-tert-butylphosphino biaryl ligands
Bruno, Nicholas C.,Buchwald, Stephen L.
supporting information, p. 2876 - 2879 (2013/07/11)
A series of palladacyclic precatalysts that incorporate electron-rich di-tert-butylphosphino biaryl ligands is reported. These precatalysts are easily prepared, and their use provides a general means of employing bulky ligands in palladium-catalyzed cross-coupling reactions. The application of these palladium sources to various C-N and C-O bond-forming processes is also described.
Phosphine-Ligated Palladium Sulfonate Palladacycles
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Paragraph 0058; 0300, (2014/01/08)
Described are palladium precatalysts, and methods of making and using them. The palladium precatalysts show improved stability and improved reactivity in comparison to previously-described palladium precatalysts.
