1307797-30-3Relevant academic research and scientific papers
Synthesis of a new tetradentate bis(imino-phosphine) ligand and its complexation with copper(I) ions
Chen, Chi-Shian,Yeh, Wen-Yann
, p. 456 - 459 (2011)
Schiff base condensation of m-phenylenediamine with two equivalents of o-(diphenylphophino)benzaldehyde products the potentially tetradentate molecule 1,3-(Ph2P(o-C6H4)CHN)2C 6H4 (1) in high yield. The reaction of 1 and [Cu(NCMe)4]BF4 affords the dinuclear complex [(1,3-(Ph2P(o-C6H4)CHN)2C 6H4)2Cu2](BF4) 2 (2) through coordination of the imino-phosphine groups. The structure of 2 has been determined by an X-ray diffraction study.
