130913-08-5Relevant articles and documents
Stereomutation of 7-Tropylionorbornane, 2-Tropyliobicyclooctane, and 2-Tropylioadamantane: Evidence for the Intermediacy of Heptafulvenes
Ikai, Keizo,Takeuchi, Ken'ichi,Kinoshita, Tomomi,Haga, Ken'ichi,Komatsu, Koichi,Okamoto, Kunio
, p. 1052 - 1058 (2007/10/02)
The perchlorates of 7-tropylionorbornane (3), 2-tropyliobicyclooctane (4), and 2-tropylioadamantane (5) were found to undergo stereomutation in acetonitrile at 25-85 deg C, as evidenced by following the change in the 13C NMR spectra of their deuter