130935-33-0Relevant academic research and scientific papers
Synthesis of Nitrogen-Containing Polycycles via Rhodium(II)-Induced Cyclization-Cycloaddition and Insertion Reactions of N-(Diazoacetoacetyl)amides. Conformational Control of Reaction Selectivity
Doyle, Michael P.,Pieters, Roland J.,Taunton, Jack,Pho, Hoan Q.,Padwa, Albert,et al.
, p. 820 - 829 (2007/10/02)
A series of diazoacetoacetamides, when treated with a catalytic quantity of a rhodium(II) carboxylate, were found to afford products derived from both a carbonyl ylide intermediate and intramolecular C-H insertion.With 3-(N-(diazoacetoacetyl)amino)propano
