1309366-56-0Relevant academic research and scientific papers
Soft secondary building unit: Dynamic bond rearrangement on multinuclear core of porous coordination polymers in gas media
Seo, Joobeom,Bonneau, Charlotte,Matsuda, Ryotaro,Takata, Masaki,Kitagawa, Susumu
, p. 9005 - 9013 (2011)
A new synthetic approach to prepare flexible porous coordination polymers (PCPs) by the use of soft secondary building units (SBUs) which can undergo multiple reversible metal-ligand bonds breaking is reported. We have prepared a zinc paddle-wheel-based t
The difference in the CO2adsorption capacities of different functionalized pillar-layered metal-organic frameworks (MOFs)
Gao, Xiang-Jing,Zheng, He-Gen
supporting information, p. 9310 - 9316 (2021/07/12)
The excessive use of fossil energy has caused the CO2concentration in the atmosphere to increase year by year. MOFs are ideal CO2adsorbents that can be used in CO2capture due to their excellent characteristics. Studies of the structure-activity relationship between the small structural differences in MOFs and the CO2adsorption capacities are helpful for the development of efficient MOF-based CO2adsorbents. Therefore, a series of pillar-layered MOFs with similar structural and different functional groups were designed and synthesized. The CO2adsorption tests were carried out at 273 K to explore the relationship between the small structural differences in MOFs caused by different functional groups and the CO2adsorption capacities. Significantly, compound6which contains a pyridazinyl group has a 30.9% increase in CO2adsorption capacity compared to compound1with no functionalized group.
