1309448-77-8

Basic information

• Product Name: N-(2-(4-chlorobenzoyl)phenyl)pivalamide
• Synonyms: N-(2-(4-chlorobenzoyl)phenyl)pivalamide
• CAS NO: 1309448-77-8
• Molecular Weight: 315.799
• Mol File: 1309448-77-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-(2-(4-chlorobenzoyl)phenyl)pivalamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-(4-chlorobenzoyl)phenyl)pivalamide(1309448-77-8)
• EPA Substance Registry System: N-(2-(4-chlorobenzoyl)phenyl)pivalamide(1309448-77-8)

Safety Data

• Hazardous Substances Data: 1309448-77-8(Hazardous Substances Data)

Upstream product

• 106-43-4 para-chlorotoluene 
• 6625-74-7 N-pivaloylaniline 
• 3282-30-2 pivaloyl chloride 
• 62-53-3 aniline 
• 104-88-1 4-chlorobenzaldehyde 
• 56619-93-3 N-(3-methoxyphenyl)pivalamide 
• 32597-37-8 N-(3-chlorophenyl)-2,2-dimethylpropionamide 
• 32597-29-8 N-(3-methylphenyl)-2,2-dimethylpropanamide 
• 1351697-59-0 N-([1,1'-biphenyl]-3-yl)pivalamide 
• 195389-97-0 N-(3-bromophenyl) pivalamide 

Relevant articles and documents

Toluene derivatives as simple coupling precursors for cascade palladium-catalyzed oxidative C-H bond acylation of acetanilides

A palladium-catalyzed cascade cross-coupling of acetanilide and toluene for the synthesis of ortho-acylacetanilide is described. Toluene derivatives can act as effective acyl precursors (upon sp3-C-H bond oxidation by a Pd/TBHP system) in the oxidative coupling between two C-H bonds. This dehydrogenative Pd-catalyzed ortho-acylation proceeds under mild reaction conditions.

Palladium-catalyzed oxidative C-H bond coupling of steered acetanilides and aldehydes: A facile access to ortho -acylacetanilides

A palladium-catalyzed oxidative C-H bond functionalization/ortho-acylation of acetanilides using easily accessible aldehyde as the acyl source is described. In the presence of a Pd(TFA)2 catalyst and tert-butylhydroperoxide at 90 °C in general, an array of ortho-acylacetanilides can be afforded in good yields.