1309646-01-2Relevant articles and documents
Synthesis of Z-alkenyl phosphorus compounds through hydroalumination and carbocupration of alkynyl precursors
Ortial, Stephanie,Montchamp, Jean-Luc
, p. 3134 - 3137 (2011)
The stereocontrolled synthesis of Z-alkenylphosphine-borane complexes is easily accomplished via the hydroalumination or carbocupration of alkynyl precursors. Z/E ratios are generally higher than 95/5. These reactions are stereocomplementary to our olefination approach.