130973-48-7Relevant academic research and scientific papers
Asymmetric metal-catalysed epoxidation of electron-deficient olefins
Bailey,Staton,Ashton,Marko,Ollis
, p. 495 - 509 (2007/10/02)
The SYN diastereospecific epoxidation of acyclic β-hydroxyketones (β-hydroxyacrylates) and cyclic β-hydroxyketones using titanium and vanadium catalysts is reported. Some initial results on the asymmetric epoxidation of these systems using the Sharpless t
On the Metal-Catalysed Epoxidation of Electron-Deficient Olefins
Bailey, Mark,Marko, Istvan E.,Ollis, W. David
, p. 2687 - 2690 (2007/10/02)
The SYN diastereoselective epoxidation of β-hydroxyacrylates and cyclic β-hydroxyketones using the Sharpless titianium and vanadium catalysts is reported.The first kinetic resolution of these systems is also described.
Stereoselective epoxidation of hydroxyenones. The synthesis of the sidechain of clerocidin
Bailey,Marko,Ollis,Rasmussen
, p. 4509 - 4512 (2007/10/02)
The sidechains of clerocidin 1 and terpentecin 2 contain a unique chiral assembly [C5H5O4]. Models for the stereospecific synthesis of this structural feature are reported.
