169690-49-7Relevant academic research and scientific papers
Octanol-accelerated Baylis-Hillman reaction
Park, Kwang-Su,Kim, Jinyoung,Choo, Hyunah,Chong, Youhoon
, p. 395 - 398 (2007)
The Baylis-Hillman reaction was greatly accelerated by use of octanol as an additive. Under the octanol-accelerated Baylis-Hillman conditions, unactivated aldehydes such as aliphatic aldehydes and aromatic aldehydes with electron-withdrawing substituents
Brucine N-oxide-catalyzed Morita-Baylis-Hillman reaction of vinyl ketones: A mechanistic implication of dual catalyst system with proline
Oh, Kyungsoo,Li, Jian-Yuan,Ryu, Jinhyang
scheme or table, p. 3015 - 3024 (2010/09/06)
The brucine N-oxide promoted Morita-Baylis-Hillman (MBH) reaction of vinyl ketones with aldehydes has been achieved. The corresponding asymmetric version of MBH reaction was also investigated, and the electron-deficient aryl aldehydes have emerged as suit
Asymmetric metal-catalysed epoxidation of electron-deficient olefins
Bailey,Staton,Ashton,Marko,Ollis
, p. 495 - 509 (2007/10/02)
The SYN diastereospecific epoxidation of acyclic β-hydroxyketones (β-hydroxyacrylates) and cyclic β-hydroxyketones using titanium and vanadium catalysts is reported. Some initial results on the asymmetric epoxidation of these systems using the Sharpless t
Stereoselective epoxidation of hydroxyenones. The synthesis of the sidechain of clerocidin
Bailey,Marko,Ollis,Rasmussen
, p. 4509 - 4512 (2007/10/02)
The sidechains of clerocidin 1 and terpentecin 2 contain a unique chiral assembly [C5H5O4]. Models for the stereospecific synthesis of this structural feature are reported.
