1309780-80-0Relevant academic research and scientific papers
Gold corroles
Alemayehu, Abraham B.,Ghosh, Abhik
, p. 106 - 110 (2011)
Although a variety of conditions proved unsuccessful for gold insertion into β-unsubstituted meso-triarylcorroles, refluxing free-base β-octabromo-meso-triarylcorrole ligands, H3[Br 8T(p-X-P)C] (X = MeO, n-Bu, CH3, H, and
Demetalation of copper undecaarylcorroles: Molecular structures of a free-base undecaarylisocorrole and a gold undecaarylcorrole
Capar, Jan,Zonneveld, Job,Berg, Steffen,Isaksson, Johan,Gagnon, Kevin J.,Thomas, Kolle E.,Ghosh, Abhik
, p. 146 - 153 (2016)
Copper undecaarylcorroles were found to undergo acid-induced demetalation with unusual ease under both reductive and nonreductive conditions. The resulting free-base undecaarylcorroles were found to be rather reactive, readily photooxygenating to yield 5/10-hydroxyisocorroles and open-chain tetrapyrroles. The use of nonreductive conditions led to 50-75% yields of undecaarylisocorroles, a new class of sterically hindered ligands, of which one proved amenable to single-crystal X-ray structural analysis. In one case, interaction of an undecaarylisocorrole with gold(III) acetate resulted in aromatization of the macrocycle and a gold undecaarylcorrole. The Au complex exhibited Au-N distances of 1.941(3)–1.965(3) ?, and no significant nonbonded interactions involving the gold. The significant solubility of this complex in organic solvents, compared with the relative insolubility of gold β-octabromo-meso-triarylcorroles, appears to be related to the lack of aurophilic and metallophilic interactions.
