1309953-42-1

Basic information

• Product Name: methyl 4-benzyloxy-2-(but-3-en-2-yloxy)-6-(2,2-dimethoxyethyl)benzoate
• Synonyms: methyl 4-benzyloxy-2-(but-3-en-2-yloxy)-6-(2,2-dimethoxyethyl)benzoate
• CAS NO: 1309953-42-1
• Molecular Weight: 400.472
• Mol File: 1309953-42-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 4-benzyloxy-2-(but-3-en-2-yloxy)-6-(2,2-dimethoxyethyl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-benzyloxy-2-(but-3-en-2-yloxy)-6-(2,2-dimethoxyethyl)benzoate(1309953-42-1)
• EPA Substance Registry System: methyl 4-benzyloxy-2-(but-3-en-2-yloxy)-6-(2,2-dimethoxyethyl)benzoate(1309953-42-1)

Safety Data

• Hazardous Substances Data: 1309953-42-1(Hazardous Substances Data)

Upstream product

• 100-51-6 benzyl alcohol 
• 6110-30-1 methyl <3,5-dihydroxy-2-(methoxycarbonyl)phenyl>acetate 
• 1309953-52-3 methyl 4-(benzyloxy)-2-(but-3-en-2-yloxy)-6-(formylmethyl)benzoate 
• 149-73-5 trimethyl orthoformate 
• 1309953-41-0 methyl 2-(methoxycarbonyl)methyl-4-benzyloxy-6-(but-3-en-2-yloxy)benzoate 
• 958747-55-2 methyl 2-(methoxycarbonyl)methyl-4-benzyloxy-6-hydroxybenzoate 

Downstream Products

• 1309953-53-4 C₅₂H₆₀O₁₀ 
• 1309953-43-2 (4-benzyloxy-2-(but-3-en-2-yloxy)-6-(2,2-dimethoxyethyl)phenyl)methanol 
• 1309953-40-9 4-benzyloxy-2-(but-3-en-2-yloxy)-6-(2,2-dimethoxyethyl)benzaldehyde 
• 1309953-44-3 1-(4-(benzyloxy)-2-(but-3-en-2-yloxy)-6-(2,2-dimethoxyethyl)phenyl)hex-5-en-1-ol 
• 1309953-39-6 ethyl 2-(5-(benzyloxy)-3-(but-3-en-2-yloxy)-2-(hex-5-enoyl)phenyl)acetate 
• 1309953-45-4 ethyl 2-((Z)-11-(benzyloxy)-5,6,7,8-tetrahydro-2-methyl-8-oxo-2H-benzo[b]oxecin-9-yl)acetate 

Relevant articles and documents

Synthesis and structural revision of phomopsin B, a novel polyketide carrying a 10-membered cyclic-ether ring

Total synthesis of the proposed structure 2 for phomopsin B was achieved by using an intramolecular olefin metathesis as a key step. The spectral data, however, did not match with those of the natural product reported. Re-examination of the reported NMR data led to the structural revision of phomopsin B to known dothiorelone A 18. The R configuration of dothiorelone A was determined by total synthesis through a cross-metathesis with a chiral olefin 19.