131001-91-7

Upstream product

• 74-85-1 ethene 
• 35450-36-3 methyl 2-bromo-5-methoxybenzoate 
• 4363-34-2 vinylboronic acid 
• 345924-12-1 5-methoxy-2-trifluoromethanesulfonyloxy benzoic acid methyl ester 
• 75927-49-0 pinacol vinylboronate 
• 2612-02-4 5-methoxysalicylic acid 
• 2905-82-0 methyl 5-methoxy-2-hydroxybenzoate 

Downstream Products

• 131001-96-2 2-<(4-methoxy-2-methoxycarbonylphenyl)methyl>-1,3-dioxane 
• 153967-96-5 5-methoxy-2-vinylbenzoic acid 

Relevant academic research and scientific papers

Rhodium(III)-Catalyzed Oxidative Intramolecular 1,1-Oxyamination of Alkenes with Protected Amino Acids to Produce Oxazoloisoindole-2,5-diones

It has been established that an electron-deficient bis(ethoxycarbonyl)-substituted cyclopentadienyl (CpE) rhodium(III) complex catalyzes the oxidative intramolecular 1,1-oxyamination of alkenes with N-benzoyl amino acids to produce oxazoloisoindole-2,5-diones. Experimental and theoretical mechanistic studies revealed that this oxidative 1,1-oxyamination proceeds via not the aza-Wacker reaction but the formation of a rhoda(III)oxazolidine initiated by the carboxylic acid-directed N?H bond cleavage.

Palladium-catalyzed Synthesis of Isocoumarin and 1-Isoquinolinone Derivatives

In the presence of copper(I) chloride, the palladium catalyzed oxidation of methyl 2-ethenylbenzoates and 2-ethenylbenzamides have been studied.This reaction was used to form isocoumarins and 1-isoquinolinones.