131002-08-9Relevant academic research and scientific papers
Rh-catalyzed oxidizing group-directed ortho C-H vinylation of arenes by vinylstannanes
Prakash, Sekar,Muralirajan, Krishnamoorthy,Cheng, Chien-Hong
supporting information, p. 13362 - 13364 (2015/08/24)
An efficient method for the synthesis of functionalized vinyl arenes from the reaction of N-methoxybenzamides or N-phenoxyacetamides with vinylstannanes via rhodium(III)-catalyzed C-H activation is described. The application of the methodology for the synthesis of a natural product thalactamine and a 7-membered ring oxepine are also demonstrated.
Palladium-catalyzed Synthesis of Isocoumarin and 1-Isoquinolinone Derivatives
Izumi, Taeko,Nishimoto, Yasuhiro,Kohei, Kunihiro,Kasahara, Akira
, p. 1419 - 1424 (2007/10/02)
In the presence of copper(I) chloride, the palladium catalyzed oxidation of methyl 2-ethenylbenzoates and 2-ethenylbenzamides have been studied.This reaction was used to form isocoumarins and 1-isoquinolinones.
