1310048-97-5Relevant academic research and scientific papers
Chemoselective Suzuki coupling of diborylmethane for facile synthesis of benzylboronates
Endo, Kohei,Ohkubo, Takahiro,Shibata, Takanori
supporting information; experimental part, p. 3368 - 3371 (2011/09/12)
The chemoselective Pd-catalyzed Suzuki-Miyaura cross-coupling reaction using a diborylmethane is reported. The use of an equimolar amount of base with a diborylmethane realized chemoselective coupling for the synthesis of various benzylboronate derivatives. Sterically hindered aryl bromides can give products in moderate to excellent yields.
