1310057-66-9Relevant academic research and scientific papers
Synthesis and characterization of a novel ruthenium nitrosyl complex and studies on photolability of coordinated NO
Ghosh, Kaushik,Kumar, Sushil,Kumar, Rajan
, p. 146 - 149 (2011)
In the present communication, we have reported the synthesis and characterization of a novel nitric oxide (NO) donating complex [Ru(L 1)(PPh3)2(NO)](ClO4) (2) derived from [Ru(L1)(PPh3)sub
Ruthenium-nitrosyl complexes derived from ligands containing two carboxylate functional groups and studies on the photolability of coordinated NO
Ghosh, Kaushik,Kumar, Sushil,Kumar, Rajan
, p. 1454 - 1461 (2014)
Ruthenium complexes [RuIII(L1)(PPh3) 2(Cl)] (1) and [RuIII(L2)(PPh3) 2(Cl)] (2) (in which L1H2 and L 2H2 are iminodiacetic
Ruthenium-nitrosyl complexes derived from ligands containing two carboxylate functional groups and studies on the photolability of coordinated NO
Ghosh, Kaushik,Kumar, Sushil,Kumar, Rajan
, p. 1454 - 1461 (2015/04/27)
Ruthenium complexes [RuIII(L1)(PPh3)2(Cl)] (1) and [RuIII(L2)(PPh3)2(Cl)] (2) (in which L1H2 and L2H2 are iminodiacetic aci
Synthesis, structure, catalytic and calculated non-linear optical properties of cis- and trans-, mer-chlorobis(triphenyl phosphine/triphenyl arsine)-dipicolinato rutheniumIII complexes
Trivedi, Manoj,Nagarajan,Kumar, Abhinav,Singh, Narendra K.,Rath, Nigam P.
, p. 29 - 38 (2011/06/24)
The new mononuclear RuIII complexes cis-, mer-[Ru(k 3-dipic)(EPh3)2Cl]·2H2O (E = P (1), As (2)), (L = 2,6-pyridyldicarboxylate; dipic) have been synthesized and characterized. The X-ray crystal struct
Ruthenium(III) complexes of dipicolinic acid with PPh3/AsPh3 as co-ligand: Synthesis and structural characterization
Sukanya, Duraiswamy,Prabhakaran, Rathinasabapathi,Natarajan, Karuppannan
, p. 2223 - 2228 (2008/10/09)
New hexa-coordinated Ru(III) complexes of the type [Ru(dipic)(EPh3)2X] have been synthesized by reacting 2,6-pyridine dicarboxylic acid (dipicolinic acid, H2dipic) with the appropriate starting complexes [RuX3(EPh3)3] (where X = Cl, Br; E = P, As). The ligand behaves as tridentate dibasic chelate. Dipicolinic acid which was expected to form a bridge between two metal centers, formed only mononuclear complexes, irrespective of the metal to ligand ratio. All the complexes have been characterized by analytical and spectroscopic (IR, electronic and EPR) data. Single-crystal X-ray analysis of the complex [Ru(dipic)(PPh3)2Cl] revealed that the coordination environment around ruthenium metal consists of an NO2P2Cl octahedron with (dipic) occupying equatorial plane. Electrochemical behavior of the complexes was studied using cyclic voltammetry. The new complexes were found to catalyze the oxidation of alcohols to aldehydes using N-methyl morpholine-N-oxide as co-oxidant.
