1310321-00-6Relevant articles and documents
Ruthenium-catalyzed hydrovinylation of N-acetylenamines leading to amines with a quaternary carbon center
Wang, Qiu-Shi,Xie, Jian-Hua,Li, Wei,Zhu, Shou-Fei,Wang, Li-Xin,Zhou, Qi-Lin
, p. 3388 - 3391 (2011/08/21)
A catalytic hydrovinylation of N-acetylenamines with ethylene is reported. This new hydrovinylation reaction is catalyzed by a ruthenium hydride complex, RuHCl(CO)(PCy3)2, providing a series of N-acetylamines with a quaternary carbon center with up to 99% yield.