1310329-93-1Relevant articles and documents
Tert-Butanesulfinylthioether ligands: Synthesis and application in palladium-catalyzed asymmetric allylic alkylation
Liu, Jibing,Chen, Guihua,Xing, Junwei,Liao, Jian
, p. 575 - 579 (2011)
A class of novel chiral SO-S-type bidentate ligands based on the tert-butylsulfinyl moiety as the sole chiral source were designed and synthesized through a simple and efficient pathway. These ligands are effective catalyst precursors for the palladium-catalyzed allylic alkylation of 1,3-diphenyl-2-propenyl acetate and moderate to good stereoselectivities (up to 84% ee) were obtained.