1310488-90-4Relevant academic research and scientific papers
Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines
Shintani, Ryo,Narui, Rintaro,Tsutsumi, Yosuke,Hayashi, Sayuri,Hayashi, Tamio
, p. 6123 - 6125 (2011)
Novel chiral phosphorus-olefin bidentate ligands have been synthesized in a few steps from a readily available enantiopure compound. These ligands have been applied to a rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl aldimines, achieving high yield and enantioselectivity.
