131104-42-2Relevant academic research and scientific papers
The first azatriphosphapentadiene, stabilized on an iron center: Formation and X-ray structural characterization
Hein, Joachim,Nieger, Martin,Niecke, Edgar
, p. 13 - 14 (1991)
Reaction of [CIP=N(2,4,6-(t-Bu)3C6H2)] (1) with Na[(η3-(2,4,6-(t-Bu)3C6H 2)PC(H)P(2,4,6-(t-Bu)3C6H 2))Fe(CO)3] (2) affords the novel 1-aza-2,3,5-triphosphapenta-1,4-diene complex [(η1,η 1-Ar*P=C(H)P-(Ar*)P=NAr*)Fe(CO)3] (3; Ar* = 2,4,6-(t-Bu)3C6H2), the structural features of which are discussed in relation to those of a carbon analogue.
