131135-76-7Relevant academic research and scientific papers
Aryl chalcogenolates of palladium(II) and platinum(II): Synthesis and structure
Gupta, Sushil K.,Khandelwal, Bishan L.
, p. 977 - 981 (2007/10/02)
Complexes of the type (I), (II) and (III) have been synthesized from the reactions between cis- and NaSeAr, and between and NaEAr (generated in situ) in ethanol-benzene at room temperature.Their structures have been established on the basis elemental analyses, conductance and molecular weight measurements, and IR, 1H and 31P NMR spectra.A trans-form for I and II and a cis-form for III have been assigned.The reaction of III (M = Pt; Ar = Ph) with has led to the formation of an interesting class of hetero binuclear complexes(DPPE)Pt(μ-EPh)2PdCl2> (IV) with phenyl chalcogen bridging.
