1311463-06-5Relevant academic research and scientific papers
Regioselective Wacker oxidation of internal alkenes: Rapid access to functionalized ketones facilitated by cross-metathesis
Morandi, Bill,Wickens, Zachary K.,Grubbs, Robert H.
, p. 9751 - 9754 (2013/09/23)
Wacka wacka: The title reaction makes use of a wide range of directing groups (DG) to enable the highly regioselective oxidation of alkenes, and occurs predictably at the distal position. Both E and Z alkenes afford valuable functionalized ketones and cross-metathesis was shown to facilitate the preparation of the starting materials. BQ=benzoquinone. Copyright
Regio-selective hydroxylation of gem-difluorinated octanes by alkane hydroxylase (AlkB)
Ramu, Ravirala,Chang, Chun-Wei,Chou, Ho-Husan,Wu, Li-Lan,Chiang, Chih-Hsiang,Yu, Steve S.-F.
supporting information; experimental part, p. 2950 - 2953 (2011/06/23)
gem-Difluoromethylene substituted molecules constitute a distinct class of fluorinated compounds. In this study, special chemistry has been developed for their preparation based on the highly selective terminal hydroxylation of these gem-difluorinated oct
