131196-51-5

Basic information

• Product Name: N-benzyl-1-phenyl-2-(trimethylsilyl)-3-butenylamine
• CAS NO: 131196-51-5
• Molecular Weight: 309.527
• Mol File: 131196-51-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzyl-1-phenyl-2-(trimethylsilyl)-3-butenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-1-phenyl-2-(trimethylsilyl)-3-butenylamine(131196-51-5)
• EPA Substance Registry System: N-benzyl-1-phenyl-2-(trimethylsilyl)-3-butenylamine(131196-51-5)

Safety Data

• Hazardous Substances Data: 131196-51-5(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 100-52-7 benzaldehyde 
• 780-25-6 N-benzylidene benzylamine 
• 113999-42-1 ethylene glycol trans-1-(trimethylsilyl)-1-propane-3-boronate 

Downstream Products

• 16939-57-4 (E)-buta-1,3-dienylbenzene 

Relevant articles and documents

The Addition of γ-(Trimethylsilyl)allylboronates to Imines

The addition of γ-(trimethylsilyl)allylboronates to imines is described and compared with the addition of simple allylboronates to imines.The addition of γ-(trimethylsilyl)allylboronates is found to be more efficient than the addition of simple allylboronates to imines.The stereoselectivity is dependant upon the nature of the imine; imines derived from aromatic aldehydes give anti products and imines derived from aliphatic aldehydes give syn products.Proof of stereochemistry was established by conversion of the anti and syn derivatives to their respective Z- and E-dienes by a methylation/E-2 elimination process.With α-alkoxy aldehydes the reaction proceeds with excellent selectivity giving the product of Felkin-Ahn addition.