13120-03-1

Basic information

• Product Name: N,N-dimethylbenzenecarboselenoamide
• Synonyms: N,N-Dimethylselenobenzamide
• CAS NO: 13120-03-1
• Molecular Formula: C₉H₁₁NSe
• Molecular Weight: 212.1503
• Mol File: 13120-03-1.mol

Chemical Properties

• Boiling Point: 256.2°C at 760 mmHg
• Flash Point: 108.8°C
• Vapor Pressure: 0.0156mmHg at 25°C
• CAS DataBase Reference: N,N-dimethylbenzenecarboselenoamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dimethylbenzenecarboselenoamide(13120-03-1)
• EPA Substance Registry System: N,N-dimethylbenzenecarboselenoamide(13120-03-1)

Safety Data

• Hazardous Substances Data: 13120-03-1(Hazardous Substances Data)

Upstream product

• 611-74-5 N,N-dimethylbenzamide 
• 5395-11-9 dimorpholinodiselenane 
• 1080-32-6 O,O-diethyl benzylphosphonate 
• 124-40-3 dimethyl amine 
• 2397-26-4 N,N-dimethyl(chlorophenylmethylene)ammonium chloride 
• 100-47-0 benzonitrile 

Downstream Products

• 33331-39-4 (Z)-N,N,N',N'-Tetramethyl-1,2-diphenyl-ethene-1,2-diamine 
• 5336-72-1 dimethyl(diphenylmethyl)amine 
• 1072006-82-6 2-(N,N-dimethylamino)-2-phenyl-cyclopropanecarboxylic acid n-butyl ester 
• 87143-88-2 N,N-dimethyl-N-(1,3-diphenyl-2-propynyl)amine 
• 2371-23-5 1,2-diphenylhexan-1-one 
• 73475-28-2 N,N-dimethyl benzenecarbotelluroamide 
• 1009-14-9 phenyl butyl ketone 

Relevant articles and documents

Reaction of diisobutylaluminium hydride with selenium and tellurium: New reagents for the synthesis of seleno- and telluro-amides

Diisobutylaluminium hydride (BuI2AlH) undergoes reaction with elemental selenium and tellurium to afford new reagents having an Al-Se or an Al-Te bond. These directly convert amides to selenoamides and telluroformamides. This affords

Selenocarbonyl synthesis using Woollins reagent

[PhP(Se)(μ-Se)]2 selenates secondary and tertiary amides to the corresponding selenoamides in 30-70% yields at 130°C in toluene and indolizine-3-aldehydes to selenoaldehydes in 40-59% yield at 25°C.

3,4,5-Tris(2,4-di-t-butyl-6-methoxyphenyl)3,4,5-triselenoxo-1,2-diselena-3,4,5-triphospholane as a Selenation Reagent

A new type of phosphorus-selenium containing heterocyclic compound, 3,4,5-tris(2,4-di-t-butyl-6-methoxyphenyl)-3,4,5-triseleno-1,2-diselena-3,4,5-triphospholane, was prepared and was allowed to react with amides to give the corresponding selenoamides in g

Copper(0)-induced aminocyclopropanation of olefins via deselenation of N,N-disubstituted aromatic selenoamides

Upon heating of a mixture of N,N-disubstituted aromatic selenoamides and several electron-deficient olefins in the presence of copper(0) powder, a novel deselenative cyclopropanation takes place to afford the corresponding aminocyclopropanes in good yields. When acrylonitrile is employed as an electron-deficient olefin, the aminocyclopentanation occurs in preference to the aminocyclopropanation by prolonging the reaction time. The obtained aminocyclopropane derivatives can be converted to the corresponding 1,4-dicarbonyl compounds upon treatment with 2 N HCl.

Tertiary selenoamide compounds are useful superoxide radical scavengers in vitro

We investigated the scavenging effects of tertiary selenoamide compounds for super oxide radicals using a highly sensitive and quantitative chemiluminescence method. At 333 nM, tertiary selenoamide compounds scavenged 25.8-81.6% of O2-/su

Facile conversion of amides and lactams to selenoamides and selenolactams using tetraethylammonium tetraselenotungstate

Chloroiminium salts generated in situ from amides and lactams using (COCl)2 or POCl3 react very readily with the new selenium transfer reagent, tetraethylammonium tetraselenotungstate, (Et 4N)2WSe4, 1

Facile synthesis of N,N-dialkylselenoamides from amides

The synthesis of the N,N-dialkylselenoamides from amides was discussed. These selenoamides were chlorinated with oxalyl chloride and then they were allowed to react with LiAlHSeH to afford the corresponding N,N-dialkylamides in moderate to good yields. Af

1,2,3,5,7-pentaselena-4,6,8-triphosphocane as the revised structure for "3,4,5-triselenoxo-1,2-diselena-3,4,5-triphospholane" determined by X-ray analysis

The structure of a new type of phosphorus-selenium containing eight-membered heterocyclic compound, 1,2,3,5,7-pentaselena-4,6,8-triphosphocane, was unambiguously determined by the X-ray analysis as the revised structure for the 3,4,5-triselenoxo-1,2-disel

The invention of radical reactions. Part XXXVII. A convenient radical synthesis of dialkyl diselenides from carboxylic acids

A new and convenient synthesis of dialkyl diselenides from carboxylic acids by Barton PTOC ester based radical chemistry is described. This method was especially successful when O-cholestan-3β-yl-2,2,2-trichloroselenoacetate and O-neopentyl selenobenzoate

Conversion of Amides, N,N,N',N'-Tetramethylurea, and Esters to the Corresponding Selenoxo Compounds by Treatment with Bis(trimethylsilyl) Selenide and BF3*OEt2

The reactions of amides and N,N,N',N'-tetramethylurea with (Me3Si)2Se in the presence of BF3*OEt2 afforded the corresponding selenoxo compounds in good yields.On the other hand, selenation of ethyl and butyl benzoates in a similar manner gave benzoin and 2,3,5,6-tetraphenyl-1,4-diselenin via selenoesters.The trapping of selenoesters was also achieved by 2,3-dimethyl-1,3-butadiene to afford cycloadducts.