13122-72-0Relevant articles and documents
Perhydrolase
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Page/Page column 51-53, (2008/12/06)
The present invention provides methods and compositions comprising at least one perhydrolase enzyme for cleaning and other applications. In some particularly preferred embodiments, the present invention provides methods and compositions for generation of peracids. The present invention finds particular use in applications involving cleaning, bleaching and disinfecting.
OXIDATION OF ISOBUTYRALDEHYDE BY MOLECULAR OXYGEN IN THE PRESENCE OF CHROMIUM ACETATE.
Sandler,Khcheyan,Kharenko,Ryabukhin,Bobylev
, p. 1244 - 1247 (2007/10/02)
Some kinetic mechanisms of the reaction of liquid-phase oxidation of isobutyraldehyde were examined. The effect of the parameters was investigated with an experimental planning method, and the optimum conditions for oxidation in the presence of chromium acetate as an alternative to cobalt were determined. Perisobutyric acid can be used for epoxidation of olefins into alpha -oxides, and isobutyric acid is used for preparation of methacrylic acid and as a fodder and feed preserver. Optimum conditions were determined for obtaining perisobutyric acid with a yield of up to 60% (the remainder was almost all isobutyric acid), i. e. , almost the same as in the presence of cobalt salts.