1312320-28-7

Basic information

• Product Name: C₂₂H₃₄O₅Si
• Synonyms: C₂₂H₃₄O₅Si
• CAS NO: 1312320-28-7
• Molecular Weight: 406.594
• Mol File: 1312320-28-7.mol

Chemical Properties

• CAS DataBase Reference: C₂₂H₃₄O₅Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₂H₃₄O₅Si(1312320-28-7)
• EPA Substance Registry System: C₂₂H₃₄O₅Si(1312320-28-7)

Safety Data

• Hazardous Substances Data: 1312320-28-7(Hazardous Substances Data)

Upstream product

• 76782-82-6 tert-Butyldimethyl(prop-2-ynyloxy)silane 
• 56681-97-1 4,4-dimethoxybutanal 
• 1312320-11-8 C₁₅H₃₀O₄Si 
• 1312320-78-7 C₁₅H₃₀O₄Si 
• 98-88-4 benzoyl chloride 
• 1312320-26-5 C₁₅H₂₈O₄Si 

Relevant articles and documents

Rh(I)-catalyzed formal [6 + 2] cycloaddition of 4-allenals with alkynes or alkenes in a tether

Rh(I)-catalyzed formal [6 + 2] cycloaddition of allenal 6 having an alkyne or alkene in a tether proceeded smoothly, giving 5-8- and 6-8-fused bicyclic ketone derivatives 7 in good to excellent yields. It was also found that cyclization of enantiomerically enriched (S)-6a (94% ee) gave cyclic ketone derivative (S)-7a in high yield with reasonable chirality transfer (86% ee). This result indicates that this cyclization proceeds through stereoselective formation of rhodacycle H′ followed by insertion of a multiple bond.