131237-52-0Relevant academic research and scientific papers
Stereochemical Control in the Ester Enolate Claisen Rearrangement. 1. Stereoselectivity in Silyl Ketene Acetal Formation
Ireland, Robert E.,Wipf, Peter,Armstrong, Joseph D.
, p. 650 - 657 (1991)
Methods for the stereoselective deprotonation and silylation of esters were systematically investigated.A kinetically controlled enolization in combination with a kinetic resolution process accounts for the selective formation of (E)- and (Z)-silyl ketene
