Stereochemical Control in the Ester Enolate Claisen Rearrangement. 1. Stereoselectivity in Silyl Ketene Acetal Formation

DOI: 10.1021/jo00002a030

Source and publish data:

Journal of Organic Chemistry p. 650 - 657 (1991)

Update date:2022-08-04

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Authors:

Ireland, Robert E.

Wipf, Peter

Armstrong, Joseph D.

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Article abstract of DOI:10.1021/jo00002a030

Methods for the stereoselective deprotonation and silylation of esters were systematically investigated.A kinetically controlled enolization in combination with a kinetic resolution process accounts for the selective formation of (E)- and (Z)-silyl ketene

Full text of DOI:10.1021/jo00002a030

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