13124-69-1Relevant articles and documents
Synthesis of Some Conjugated Caradienes from 3-Carene by the Wittig Reaction and Their Reactivity in the Diels-Alder Reaction
Lajunen, Marja
, p. 13181 - 13198 (1994)
The applicability of the Wittig reaction for the preparation of conjugated cis-caradienes was studied by the preparation of 4-methyl-3(10)-carene (27).The method was applied for the study of the synthesis of 3-vinyl-3-apocarene (6), 4-methylene-3(10)-carene (7), 4-methyl-2-methylene-3(10)-carene (8), 4-isopropenyl-3-carene (9) and 4-isopropenyl-3-caren-2a-ol (11) starting from 3-carene (20).The reactivity of conjugated cis-caradienes 6,7 and 9 in the Diels-Alder reaction has also been studied.
Selective oxidation of primary alcohols with quinolinium chlorochromate
Singh, Jasvinder,Kad, G. L.,Vig, Shikha,Sharma, Munisha,Chhabra, B. R.
, p. 272 - 274 (2007/10/03)
Selective oxidation of primary alcohol in the presence of a secondary alcohol with quinolinium chlorochromate (QCC) has been achieved with a mild, stable and very efficient reagent. Its mechanistic and comparative study with isoquinolinium chlorochromate (IQCC) has also been reported.
LIGHT-MEDIATED TRANSFORMATIONS OF OLEFINS INTO ALCOHOLS: REACTIONS OF HYDROXYL RADICALS WITH CYCLOALKENES
Sonawane, H. R.,Nanjundiah, B. S.,Kelkar, R. G.
, p. 6673 - 6682 (2007/10/02)
Reactions of hydroxyl radicals, generated by photodecomposition of hydrogen peroxide in acetonitrile, with a wide variety of cycloalkenes have been examined.The results show that the major reaction is the addition of hydroxyl radicals to the less substituted end of the double bond, furnishing the secondary alcohols.The reactivity pattern and the observed regio- and stereoselectivity clearly reveal that the steric parameters associated with the substrates play a dominant role in directing the addition reactions.More importantly, this study led to the development of a new methodology for the facile conversions of olefins essentially into secondary alcohols, and includes a few examples which demonstrate the potential of the method.