131284-20-3

Upstream product

• 131284-16-7 Methyl 4-deoxy-6-O-(1-methoxy-1-methylethyl)-2-O-(cis-1-propenyl)-α-L-threo-4-hexenopyranoside 
• 131284-30-5 Benzyl 6-O-allyl-3,4-O-isopropylidene-2-O-(1-propenyl)-β-D-galactopyranoside 
• 131284-17-8 Methyl 3-O-acetyl-4-deoxy-6-O-(1-methoxy-1-methylethyl)-2-O-(cis-1-propenyl)-α-L-threo-4-hexenopyranoside 
• 937-14-4 3-chloro-benzenecarboperoxoic acid 
• 131284-27-0 Methyl 3,4,6-tri-O-methyl-2-O-(cis-1-propenyl)-α-D-galactopyranoside 
• 131284-33-8 Methyl 3,4,6-tri-O-methyl-2-O-(cis-1-propenyl)-β-D-galactopyranoside 

Relevant academic research and scientific papers

NEW SYNTHETIC PATHWAYS TO 5-C-ALKOXYPYRANOSIDES AND TO HEXOS-5-ULOSE DERIVATIVES

Several new 5-C-alkoxy-D-galactopyranosides have been obtained by oxidation of 4-deoxy-α-L-threo-hex-4-enopyranosides (easily available from β-D-galactopyranosides) with MCPBA in alcoholic solvents.They have been converted into the so far unreported L-ara

Meta-chloroperbenzoic acid as a selective reagent for the removal of O-propenyl groups. Its use in the synthesis of some d-galactopyranoside and 4-deoxy-1-threo-4-hexenopyranoside derivatives

Meta-chloroperbenzoic acid can be used as a mild and selective reagent for the removal of the O-propenyl group in the deprotection sequence of allyl protected hydroxyl functions. Its use is illustrated in four synthetic pathways, leading, respectively, to