1312883-75-2Relevant academic research and scientific papers
Synthesis and spectral properties of dodecaphenyl-substituted planar binuclear naphthalocyanine magnesium complex sharing a common benzene ring
Dubinina, Tatiana V.,Borisova, Natalia E.,Paramonova, Kseniya V.,Tomilova, Larisa G.
, p. 165 - 167 (2011)
Dodecaphenyl-substituted planar binuclear naphthalocyanine magnesium complex possessing an intense absorption in the near IR region up to 1100 nm has been synthesized on the basis of novel 2,3-dicyano-6,7-diphenylnaphthalene.
Phenyl-substituted planar binuclear phthalo- and naphthalocyanines: Synthesis and investigation of physicochemical properties
Dubinina, Tatiana V.,Trashin, Stanislav A.,Borisova, Natalia E.,Boginskaya, Irina A.,Tomilova, Larisa G.,Zefirov, Nikolay S.
experimental part, p. 1471 - 1480 (2012/03/27)
Dodeca-phenyl-substituted planar binuclear phthalocyanine magnesium complexes with an extended π-conjugation system were synthesized with high yields. Two approaches to the extension of the π-system were presented: extension of an aromatic bridge or a peripheral π-system. A maximum of near-IR absorption at 972 nm was observed in the case of the planar binuclear naphthalocyanine sharing a common benzene ring. Binuclear phthalo- and naphthalocyanines were characterized by high resolution MALDI-TOF mass spectrometry, UV/Vis/NIR and 1H NMR spectroscopy. DFT modeling of the structure and chemical shift GIAO calculations were made. The formation of nanoaggregates in a solid film was proven using AFM. The electrochemical properties of binuclear naphthalocyanine complexes were investigated for the first time.
