131291-41-3

Upstream product

• 141042-89-9 (1S,6S)-6-Hydroxymethyl-cyclohex-2-enol 
• 141042-92-4 (1S,2R,3S,6S)-2-Benzyloxy-3-benzyloxymethyl-7-oxa-bicyclo[4.1.0]heptane 
• 140934-09-4 (1R,2R,3S,6R)-2-Benzyloxy-3-benzyloxymethyl-7-oxa-bicyclo[4.1.0]heptane 
• 140934-04-9 (1R,5S,6R)-6-Benzyloxy-5-benzyloxymethyl-cyclohex-2-enol 
• 100-39-0 benzyl bromide 
• 130970-84-2 DL-(1,3/2)-1,2-dihydroxy-3-hydroxymethyl-5-cyclohexene 
• 130970-85-3 rac-((((1R,2R,6R)-6-((benzyloxy)methyl)cyclohex-3-ene-1,2-diyl)bis-(oxy))bis(methylene))dibenzene 

Downstream Products

• 140934-06-1 C₃₈H₄₁NO₅S 
• 221371-39-7 (1S,2S,3R,4R)-1-amino-3,4-di-O-benzyl-5-(benzyloxymethyl)cyclohex-5-ene-2,3,4-triol 
• 38231-86-6 valienamine 
• 140934-05-0 (1R,4S,5R,6R)-5,6-Bis-benzyloxy-4-benzyloxymethyl-cyclohex-2-enol 
• 131291-48-0 DL-(1,3,4/2,6)-3,4-diacetamido-1,2-di-O-benzyl-6-benzyloxymethyl-1,2-cyclohexanediol 
• 131291-52-6 (1SR,2RS,3RS,4RS,6SR)-7-acetyl-2,3-dibenzyloxy-4-benzyloxymethyl-7-azabicyclo<4.1.0>heptane 
• 131291-51-5 DL-(1,4/2,3,6)-3,4-diacetamido-6-acetoxymethyl-1,2-di-O-acetyl-1,2-cyclohexanediol 
• 131291-51-5 DL-(1,3/2,4,6)-3,4-diacetamido-6-acetoxymethyl-1,2-di-O-acetyl-1,2-cyclohexanediol 
• 131291-51-5 DL-(1,3,4/2,6)-3,4-diacetamido-6-acetoxymethyl-1,2-di-O-acetyl-1,2-cyclohexanediol 
• 131291-40-2 DL-(1,3,4/2,6)-3,4-diamino-6-hydroxymethyl-1,2-cyclohexanediol 
• 131291-40-2 DL-(1,3/2,4,6)-3,4-diamino-6-hydroxymethyl-1,2-cyclohexanediol 
• 131291-40-2 DL-(1,4/2,3,6)-3,4-diamino-6-hydroxymethyl-1,2-cyclohexanediol 

Relevant academic research and scientific papers

INTRAMOLECULAR AMINO DELIVERY REACTIONS FOR THE SYNTHESIS OF VALIENAMINE AND ANALOGUES

Iodocyclization and sigmatropic rearrangement reactions of N-substituted carbonimidothioates are used to prepare valienamine (1), 7-norvalienamine (8), and the valienamine-based pseudo-disaccharide 12. Key words: carbonimidothioates; iodocyclization; rearrangement; glucosidase inhibitors; pseudo disaccharides

Synthesis of DL-2-amino-2-deoxyvalidamine and its three diastereoisomers

DL-2-Amino-2-deoxyvalidamine (5), 2-amino-5a-carba-2-deoxy-α-DL-glucopyranosylamine, and related 2-amino-5a-carba-2-deoxy-DL-hexopyranosylamines having the β-gluco (6), and α- (7) and β-manno configurations (8) have been synthesized from two 1,2-anhydro-3