131295-29-9Relevant academic research and scientific papers
122. Rh(II)-Catalyzed Isomerizations of Cyclopropenes. Evidence for Rh(II)-Complexed Vinylcarbene Intermediates
Mueller, Paul,Pautex, Nicole,Doyle, Michael P.,Bagheri, Vahid
, p. 1233 - 1241 (1990)
The thermocatalytic rearrangements of cyclopropenes 1-4 have been investigated in the presence of Rh(II)perfluorobutyrate. 1,2,3-Triphenylcyclopropene (1a) undergoes rearrangement to diphenylindene 5a or, with alkoxycyclopropene derivatives, to α,β-unsatu
