122. Rh(II)-Catalyzed Isomerizations of Cyclopropenes. Evidence for Rh(II)-Complexed Vinylcarbene Intermediates

DOI: 10.1002/hlca.19900730513

Source and publish data:

Helvetica Chimica Acta p. 1233 - 1241 (1990)

Update date:2022-08-02

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Authors:

Mueller, Paul

Pautex, Nicole

Doyle, Michael P.

Bagheri, Vahid

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Article abstract of DOI:10.1002/hlca.19900730513

The thermocatalytic rearrangements of cyclopropenes 1-4 have been investigated in the presence of Rh(II)perfluorobutyrate. 1,2,3-Triphenylcyclopropene (1a) undergoes rearrangement to diphenylindene 5a or, with alkoxycyclopropene derivatives, to α,β-unsatu

Full text of DOI:10.1002/hlca.19900730513

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