131316-89-7

Upstream product

• 116302-67-1 2,3,4,6,7-penta-O-acetyl-L-glycero-α-D-manno-heptopyranosyl bromide 
• 131289-49-1 methyl 2,4-di-O-acetyl-6-O-benzoyl-3-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-L-glycero-α-D-manno-heptopyranoside 
• 40653-15-4 methyl 2,3,4-tri-O-benzyl-α-D-manno-hexodialdo-1,5-pyranoside 
• 131289-44-6 methyl 6-O-benzoyl-7-O-(tert-butyldimethylsilyl)-L-glycero-α-D-manno-heptopyranoside 
• 104486-80-8 1,2,3,4,6,7-hexa-O-acetyl-L-glycero-α-D-manno-heptopyranose 
• 131289-52-6 methyl 2,4-di-O-acetyl-6-O-benzoyl-7-O-(tert-butyldimethylsilyl)-3-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-L-glycero-α-D-manno-heptopyranoside 
• 127588-70-9 (R)-2-(Isopropoxy-dimethyl-silanyl)-1-((2R,3S,4S,5S,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-ethanol 
• 122622-12-2 methyl 2,3,4,6,7-penta-O-acetyl-L-glycero-α-D-manno-heptopyranoside 
• 122588-51-6 methyl-2,3,4-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside 
• 131289-43-5 methyl 6-O-benzoyl-2,3,4-tri-O-benzyl-7-O-(tert-butyldimethylsilyl)-L-glycero-α-D-manno-heptopyranoside 

Relevant academic research and scientific papers

Synthesis of methyl 3-O-(α-D-glucopyranosyl)-7-O-(L-glycero-α-D-manno-heptopyranosyl)-L-glycero-α-D-manno-heptopyranoside

The title trisaccharide glycoside, which is related to part of the core region of the lipopolysaccharide from Salmonella, and the disaccharide glycosides methyl 3-O-α-D-glucopyranosyl-L-glycero-α-D-manno-heptopyranoside and methyl 7-O-L-glycero-α-D-manno-heptopyranosyl-L-glycero-α-D-manno-heptopyranoside have been synthesised.Methyl 2,3,4-tri-O-benzyl-L-glycero-α-D-manno-heptopyranoside, obtained via a one-carbon elongation at C-6 of methyl 2,3,4-tri-O-benzyl-α-D-manno-hexodialdo-1,5-pyranoside, was used as precursor both for the heptosyl donor and acceptor.