131327-54-3Relevant academic research and scientific papers
Rhodium carbenoid mediated cyclisations. Part 6. Synthesis of cyclic sulphoxonium ylides
Moody, Christopher J.,Taylor, Roger J.
, p. 6525 - 6544 (2007/10/02)
Treatment of diazo sulphoxides with rhodium(11) acetate gives stable five- and six- membered cyclic sulphoxonium ylides.
RHODIUM CARBENOID MEDIATED CYCLISATIONS. SYNTHESIS AND X-RAY STRUCTURES OF CYCLIC SULPHOXONIUM YLIDES
Moody, Christopher J.,Slawin, Alexandra M. Z.,Taylor, Roger J.,Williams, David J.
, p. 6009 - 6012 (2007/10/02)
Rhodium (II) acetate catalysed decomposition of the diazo sulphoxides (1) and (3) gives the cyclic sulphoxonium ylides (2) and (4); the structures of (2c) and (4a) were confirmed by X-ray crystallography.
