1313428-94-2Relevant academic research and scientific papers
Suzuki-Miyaura reactions of the bis(triflates) of 1,3- and 1,4-dihydroxythioxanthone. Electronic and steric effects on the site-selectivity
Zinad, Dhafer Saber,Feist, Holger,Villinger, Alexander,Langer, Peter
, p. 711 - 721 (2012/01/05)
The palladium(0)-catalyzed Suzuki cross-coupling reactions of the bis(triflates) of 1,3- and 1,4-dihydroxythioxanthone afforded various aryl-substituted thioxanthones. While the Suzuki reactions of the bis(triflate) derived from 1,3-dihydroxythioxanthone proceeded by site-selective attack in favor of position 3, the reactions of the bis(triflate) of 1,4- dihydroxythioxanthone proceeded in favor of position 1. The site-selectivity is controlled by steric and electronic parameters.
Site-selective Suzuki-Miyaura reactions of the bis(triflate) of 1,3-dihydroxythioxanthone
Zinad, Dhafer Saber,Hussain, Munawar,Akrawi, Omer Adeeb,Villinger, Alexander,Langer, Peter
, p. 3451 - 3454 (2011/06/27)
The palladium(0)-catalyzed Suzuki cross-coupling reaction of the bis(triflate) of 1,3-dihydroxythioxanthone afforded various aryl-substituted thioxanthones. The reactions proceeded with very good site-selectivity in favour of position 3, due to steric reasons.
