1313511-86-2

Basic information

• Product Name: (5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane
• CAS NO: 1313511-86-2
• Molecular Weight: 637.061
• Mol File: 1313511-86-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane(CAS DataBase Reference)
• NIST Chemistry Reference: (5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane(1313511-86-2)
• EPA Substance Registry System: (5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane(1313511-86-2)

Safety Data

• Hazardous Substances Data: 1313511-86-2(Hazardous Substances Data)

Upstream product

• 83632-96-6 6-tetrahydropyranyloxy-4-hexen-1-ol 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 1313511-85-1 (2R,5S,E)-1-((tert-butyldimethylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2-methyl-9-((tetrahydro-2H-pyran-2-yl)oxy)non-7-en-4-one 
• 1313511-73-7 (2S,E)-N-methoxy-2-((4-methoxybenzyl)oxy)-N-methyl-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-enamide 
• 1313511-94-2 C₁₉H₂₆O₆ 
• 1313511-84-0 (2S,E)-2-((4-methoxybenzyl)oxy)-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-en-1-ol 
• 1313511-83-9 C₁₇H₃₄O₄Si 
• 1313511-82-8 (2S,E)-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-ene-1,2-diol 

Downstream Products

• 1313511-87-3 (5S,6S,8R,E)-6,9-bis((tert-butyldimethylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-8-methylnon-2-en-1-ol 
• 1313511-88-4 ((2S,3S)-3-((2S,3S,5R)-3,6-bis((tert-butyldimethylsilyl)oxy)-2-((4-methoxybenzyl)oxy)-5-methylhexyl)oxiran-2-yl)methanol 
• 1313511-89-5 (5S,7R)-5-((S)-1-((4-methoxybenzyl)oxy)-2-((2R,3S)-3-vinyloxiran-2-yl)ethyl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane 

Relevant articles and documents

A stereoselective total synthesis of 7,8-O-isopropylidene iriomoteolide-3a

A stereoselective total synthesis of 7,8-O-isopropylidene iriomoteolide-3a has been achieved by using Yamaguchi esterification, Julia-Kocienski olefination, organocatalytic α-oxidation, and ring-closing metathesis reaction as key bond-forming steps.