131364-97-1Relevant academic research and scientific papers
Alcynylsilanes functionnels I. Synthese regiospecifique par voie organozincique d'alcools homopropargyliques trialkylsilyles α'- ou ω'-chlores
Mesnard, D.,Miginiac, L.
, p. 127 - 137 (1990)
In many cases, the reaction between α- or ω-chloro carbonyl derivatives and organozincs prepared from halides R3Si-CC-CH2Br is chemo- and regioselective: it affords, in a good yield, trialkylsilyl homopropargylic alcohols α'- or ω'-substituted by a chlorine atom.This behaviour is different of this of organoaluminiums which lead mainly to trialkylsilyl α-allenyl α'- or ω'-chlorinated alcohols.
Allenylsilanes fonctionnels: synthese regioselective par voie organoaluminique d'alcools alleniques trimethylsilyles α'- ou ω'-chlores
Mesnard, Danielle,Miginiac, Leone
, p. 299 - 309 (2007/10/02)
In many cases, the reaction between α- or ω-chloro carbonyl derivatives and organoaluminium compound prepared from Me3Si-CC-CH2Br is chemo- and regioselective: it affords, in a good yield, trimethylsilyl α-allenyl alcohols α'- or ω'-substituted by a chlorine atom; some of these functional alcohols have produced oxygenated heterocycles.
