1313735-48-6

Basic information

• Product Name: (6-methylpyridin-2-yl)methyl 4-methylbenzenesulfonate
• Synonyms: (6-methylpyridin-2-yl)methyl 4-methylbenzenesulfonate
• CAS NO: 1313735-48-6
• Molecular Weight: 277.344
• Mol File: 1313735-48-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (6-methylpyridin-2-yl)methyl 4-methylbenzenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: (6-methylpyridin-2-yl)methyl 4-methylbenzenesulfonate(1313735-48-6)
• EPA Substance Registry System: (6-methylpyridin-2-yl)methyl 4-methylbenzenesulfonate(1313735-48-6)

Safety Data

• Hazardous Substances Data: 1313735-48-6(Hazardous Substances Data)

Upstream product

• 1073-23-0 2,6-lutidine N-oxide 
• 98-59-9 p-toluenesulfonyl chloride 
• 1122-71-0 2-(Hydroxymethyl)-6-methylpyridine 

Downstream Products

• 863971-65-7 N-ethyl-N-((6-methylpyridin-2-yl)methyl)ethanamine 
• 14993-80-7 2-(6-methylpyridin-2-yl)acetonitrile 
• 60398-59-6 ((6-methylpyridin-2-yl)methyl)diphenylphosphine oxide 

Relevant articles and documents

Metal-free C(sp3)-H bond sulfonyloxylation of 2-alkylpyridines and alkylnitrones

Pyridin-2-ylmethyl tosylate derivatives are obtained in high yields from 2-alkylpyridine 1-oxides via a [3,3]-sigmatropic rearrangement of the adduct between 2-alkylpridine 1-oxides with benzenesulfonyl chlorides. Moreover, alkylnitrones also undergo [3,3]-sigmatropic rearrangement to give α-tosylated ketones after hydrolysis. Substitution reactions with nucleophiles then lead to diverse useful functionalizations for the synthesis of pincer ligands.