60398-59-6Relevant articles and documents
Copper(II) Acetate-Catalyzed Synthesis of Phosphorylated Pyridines via Denitrogenative C?P Coupling between Pyridotriazoles and P(O)H Compounds
Shen, Ruwei,Dong, Chao,Yang, Jianlin,Han, Li-Biao
supporting information, p. 4252 - 4258 (2018/10/02)
A new inexpensive copper-catalyzed denitrogenative C?P coupling reaction of pyridotriazoles with P(O)H compounds has been developed. The reaction proceeds via a process of copper-catalyzed P(O)?H insertion into the pyridyl carbene intermediates generated in situ from pyridotriazoles. This reaction provides a new and effective method for the synthesis of a variety of 2-picolylphosphoryl compounds. (Figure presented.).